Rubber chemicals

Acetoneanile TMQ

1,2-Dihydro-2,2,4-trimethylquinoline (TMQ) is used as primary antioxidant in rubber compounds to protect the rubber articles from oxidative degradation at ambient as well as higher temperatures. TMQ represents a group of antioxidants based on polymerized Aniline-Acetone condensation products.

Acetoneanile TMQ is widely used in the manufacture of truck & bus radials, passenger Radials, car tires, steel cord conveyor belts and other technically sophisticated rubber products.

More about TMQ

Diphenylguanidine

Diphenylguanidine is a secondary vulcanization accelerator that activates thiazoles (MBT, MBTS), thiurams (TMTM, TMTD) or sulfenamide (CBTS) in NR (0.1-0.5phr), SBR (0.15 - 0.75phr) and NBR (0.1-0,5phr) applications. Due to discoloration it is generally used for dark or black color products (silica containing tires, mechanical goods, hard rubber products, footwear, adhesives, diaphragms, rubber gloves, medical devices, dialysis equipment, rubber in elasticized undergarments and clothing, rubber pillows, sponges, toys). Provides good scorch and storage stability.

More about DPG

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Acetoneanile TMQ

CAS No.: 26780-96-1 H.S. Code: 3812.30.2000

Chemical Name: Polymerized 2,2,4 – trimethyl – 1,2 – dihydroquinoline

Synonyms: 1,2-Dihydro-2,2,4-trimethylquinoline oligomers, Acetonanil, Acetonanyl, Acetone Anil, DHMQ, Hydro-2,2,4-trimethylquinoline oligomers, Poly(1,2-dihydro-2,2,4-trimethylquinoline), Polymerized 1,2-Dihydro-2,2,4-trimethylquinoline, TDQ, TMDQ, TMQ, Trimethyldihydroquinoline polymer.

Main applications:

  • Slightly staining non-blooming antioxidant in the production of rubber compounds for tyres, tyres retreads and heavily stressed technical rubber goods (tubes, buffers, insulating electric wires & cables, conveyor and transmission belts, steam hoses, break linings, oil seals, profiles, boots and footwear soles and heels) based on NR, IR, SBR, NBR and polybutadiene. 0.5 - 3.0 phr loadings enhance their flex life and provide long-time thermal-oxidative protection. Excellent antiozonant for CR, partially replaces para-phenylenediamine (PPDA) antiozonants. Inhibitor of oxidation catalyzed by copper and manganese.

Other applications:

  • Peroxide cure (0.25 - 1.0 phr) of EPR/EPDM and NBR compounds.
  • Antioxidant protection of latexes.

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Quality Data:

Parameters Garanteed value Test method
Appearance Brownish granules, free from agglomerates Visual
Assay, %, MIN. 90 Potentiometric titration of the basic nitrogen, TM743
Softening point, °С: 83 - 95 Ring & Ball, ASTM E28-67
Isopropyl bis-aniline content %, MAX 0,5 HPLC, QA5026-01
Volatiles content, %, MAX 0,4 2hrs @ 105 °С, ISO787-281
Ash content, %, MAX 0,25 2hrs @ 750 °С, ASTM D4574

Guaranteed storage life: 12 months from the date of manufacturing

Packing: 25 kg multi-wall paper bags stacked on pallets (900 kgs net/pallet) and wrapped in a shrink film.

Transportation information:

  • UN number: 3077
  • UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
  • UN Class: 9
  • UN Packing Group: III
  • Environmental Hazards: Self-classification (in accordance with GHS/CLP classification criteria): 
    • Hazards to the aquatic environment: Chronic Category 2
    • H411: Toxic to aquatic life with long lasting effects.
  • Special precautions for user: A number of restrictions may apply to materials subject to local/ national/regional classifications requirements. Please refer to the appropriate regulation for specific details regarding classification requirements and restrictions.

Labelling:

  • N Symbol
  • R/S phrases: R52/53, S61.

Diphenylguanidine

CAS No.: 102-06-7
EINECS No.: 203-002-1
H.S. Code: 2925.29.0000
EC INDEX No.: 612-149-00-4

Chemical Name: N,N’-Diphenylguanidine

Synonyms: 1,3-Difenylguanid, 1,3-Diphenylguanidine, Diphenylguanidine, DFG, DPG, DPG accelerator, 1,3-Difenylguanid, Guanidine, Melaniline, sym-Diphenylguanidine

Main applications:

  • Secondary vulcanization accelerator, it activates thiazoles (MBT, MBTS), thiurams (TMTM, TMTD) or sulfenamide (CBTS) in NR (0.1-0.5phr), SBR (0.15 - 0.75phr) and NBR (0.1-0,5phr) applications. With bitter taste, not suitable for products connected with foodstuffs. Due to discoloration it is generally used for dark or black color products (silica containing tyres, mechanical goods, hard rubber products, footwear, adhesives, condoms and diaphragms, rubber gloves, medical devices, renal dialysis equipment, rubber in elasticized undergarments and clothing, rubber pillows, sponges, toys). Provides good scorch and storage stability;
  • Acts as plasticizer on chloroprene rubber in conjunction with sulfur and TMTM.

Secondary applications: Primary material for standardizing acids.

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Quality Data:

Parameters Garanteed value Test method
Appearance Cylindrical granules Visual
Assay, % min 97 Titration
Melting temperature, initial °С, min: 145,0 Capillary method
Melting temperature, final °С, max: 148,0±2,0 Capillary method
Dedusting agent (paraffinic oil) content, %, max: 0,7-2,0 Extracting
Ash content, %, max: 0,3 At 750 °С
Mass fraction of volatiles, %, max: 0,3 2 hours @ 70 °С

Guaranteed storage life: 12 months from the date of manufacturing in its original packing.

Packing: 20 kg net multi-wall laminated paper bags with PE lining stacked on pallets (640 kg net/pallet) and wrapped in a shrink film, 500 kg net IBC.

Transportation information:


Land transport
(ADR/RID)
Sea transport (IMDG) Air transport
(ICAO/IATA)
UN-Number: 2811 2811 2811
UN Proper shipping name: TOXIC SOLID ORGANIC, N.O.S., (1,3-DIPHENYLGUANIDINE) TOXIC SOLID ORGANIC, N.O.S., (1,3-DIPHENYLGUANIDINE) TOXIC SOLID ORGANIC, N.O.S., (1,3-DIPHENYLGUANIDINE)
Transport hazard Class: 6.1 6.1 6.1
Packaging group: III III III
Environmental hazards: TOXIC SOLID ORGANIC, N.O.S. TOXIC SOLID ORGANIC, N.O.S.,
Marine pollutant
TOXIC SOLID ORGANIC, N.O.S.

Note: A number of restrictions may apply to materials subject to local/ national/regional classifications requirements. Please refer to the appropriate regulation for specific details regarding classification requirements and restrictions.

Labelling:

  • Xn Symbol
  • N Symbol
  • R/S phrases: R22-36/37/38-51/53-62, S2-26-36/37/39-61

Logistics

Khimprom have established an advanced infrastructure for supplying rubber chemicals to its customers throughout the world including custom clearance, storage and delivery to doors.

  • Bulgaria
  • Brazil
  • Germany
  • India
  • Iran
  • Italy
  • Lithuania
  • Luxembourg
  • Poland
  • Romania
  • Serbia
  • Slovakia
  • Slovenia
  • Turkey
  • Finland
  • France
  • South Africa
Map supplies Acetoneanile TMQ and DPG's produced at PJSC Khimprom

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Address:
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